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台大化工系網站英文版

郝漢明 助理教授 / Han-Ming Hau Assistant Professor

Energy MaterialsElectrochemistrySynthesis Science (02)3366-1901 N512 CheE BLDG.II 化工二館(鄭江樓) 助理教授 郝漢明 Han-Ming Hau hmhau@ntu.edu.tw Assistant Professor 電化學與能源材料實驗室 Electrochemistry and Energy Materials Lab 能源材料電化學合成科學
    • Education Background
      • University of Southern California, B.S., Chemical Engineering, 2019
      • University of California-Berkeley, Ph.D., Materials Science and Engineering, 2024
      • Lawrence Berkeley National Laboratory, Postdoc., 2025

     

    • Research Topic
      • Our research centers on electrochemistry and energy materials to address the growing demand for energy storage, which results in need for low-cost, sustainable battery technologies. Novel cathode structures, such as disordered rocksalt and partially disordered spinel, offer high energy density and broad compositional flexibility. The research will focus on the synthesis of Earth-abundant cathode materials for Li-ion batteries and investigating their ion-transport mechanisms and structural properties using advanced electrochemical and structural characterization techniques.
      • We will also apply electrochemical/solution intercalation and exfoliation to modify two-dimensional (2D) material thin films. By controlling intercalant chemistry, electrochemical potential, and reaction kinetics, the research aims to investigate transport properties and phase transformations during intercalation and develop tunable control of structural and electronic properties of 2D materials for applications in electronics and energy storage.

     

    • Recent Research Topic
  • 1. Best Poster Award, International Meeting on Lithium Batteries (2024)

    1. Kodalle, T.; Fei, Y.; Grass, M.; Cheng, D.; Avvaru, V. S.; Halder, A.; Kruse, K.; Hau, H. M.; et al. Solvent Determines the Formation Pathway in Sol–Gel Synthesized Disordered Rock Salt Material for Lithium-Ion Battery Application. Nano Lett. 2025, 25 (30), 11647–11654.1
    2. Hau, H. M.; Holstun, T.; Lee, E.; Rinkel, B. L. D.; Mishra, T. P.; Markuson DiPrince, M.; et al. Disordered Rocksalts as High-Energy and Earth-Abundant Li-Ion Cathodes. Adv. Mater. 2025, 37 (46), 2502766.
    3. Yang, X.; Chen, Y.; Wei, G.; Diallo, M. S.; Avdeev, M.; Hau, H. M.; Qiu, H.; Ji, H.; et al. Harnessing Cation Disorder for Enhancing Ionic Conductivity in Lithium Inverse Spinel Halides. ACS Energy Lett. 2025, 10 (3), 1338–1346.
    4. Holstun, T.; Mishra, T. P.; Huang, L.; Hau, H. M.; Anand, S.; Yang, X.; Ophus, C.; et al. Accelerating the Electrochemical Formation of the δ Phase in Manganese-Rich Rocksalt Cathodes. Adv. Mater. 2025, 37 (6), 2412871.
    5. Moździerz, M.; Holstun, T.; Cai, Z.; Lee, G. H.; Hau, H. M.; Yang, X.; Chen, Y.; et al. Tuning Cation (Dis)Order in Cr-Based Li-Excess Oxide Cathode Materials to Improve Li⁺ Transport Properties. Adv. Energy Mater. 2025, Article 2502157.
    6. Kim, B.; Zhong, P.; Choi, Y.; Anand, S.; Hau, H. M.; Deng, B.; Ceder, G. Oxygen Dimerization–Driven Cation Migration Induces Voltage Hysteresis in Disordered Rocksalt Cathodes. J. Am. Chem. Soc. 2024, 147 (1), 223–233.
    7. Hau, H. M.; Mishra, T.; Ophus, C.; Huang, T. Y.; Bustilo, K.; Sun, Y.; Yang, X.; et al. Earth-Abundant Li-Ion Cathode Materials with Nanoengineered Microstructures. Nat. Nanotechnol. 2024, 19 (12), 1831–1839.
    8. Yang, X.; Gupta, S.; Chen, Y.; Sari, D.; Hau, H. M.; Cai, Z.; Dun, C.; Qi, M.; Ma, L.; et al. Fast Room-Temperature Mg-Ion Conduction in Clay-Like Halide Glassy Electrolytes. Adv. Energy Mater. 2024, 14 (26), 2400163.
    9. Huang, T. Y.; Cai, Z.; Crafton, M. J.; Giovine, R.; Patterson, A.; Hau, H. M.; et al. Chemical Origin of In Situ Carbon Dioxide Outgassing from a Cation-Disordered Rock Salt Cathode. Chem. Mater. 2024, 36 (13), 6535–6546.
    10. Cai, Z.; Ouyang, B.; Hau, H. M.; Chen, T.; Giovine, R.; Koirala, K. P.; Li, L.; Ji, H.; Ha, Y.; et al. In Situ Formed Partially Disordered Phases as Earth-Abundant Mn-Rich Cathode Materials. Nat. Energy 2024, 9 (1), 27–36.
    11. Huang, T. Y.; Cai, Z.; Crafton, M. J.; Kaufman, L. A.; Konz, Z. M.; Bergstrom, H. K.; Hau, H. M.; et al. Quantitative Decoupling of Oxygen-Redox and Manganese-Redox Voltage Hysteresis in a Cation-Disordered Rock Salt Cathode. Adv. Energy Mater. 2023, 13 (21), 2300241.
    12. Huang, L.; Zhong, P.; Ha, Y.; Cai, Z.; Byeon, Y. W.; Huang, T. Y.; Sun, Y.; Xie, F.; Hau, H. M.; et al. Optimizing Li-Excess Cation-Disordered Rocksalt Cathode Design through Partial Li Deficiency. Adv. Energy Mater. 2023, 13 (4), 2202345.
    13. Cai, Z.; Zhang, Y. Q.; Lun, Z.; Ouyang, B.; Gallington, L. C.; Sun, Y.; Hau, H. M.; et al. Thermodynamically Driven Synthetic Optimization for Cation-Disordered Rock Salt Cathodes. Adv. Energy Mater. 2022, 12 (21), 2103923.
    14. Fleetham, T.; Golden, J. H.; Idris, M.; Hau, H. M.; Muthiah Ravinson, D. S.; et al. Tuning State Energies for Narrow Blue Emission in Tetradentate Pyridyl–Carbazole Platinum Complexes. Inorg. Chem. 2019, 58 (18), 12348–12357.